Leather and fur - Determination of formaldehyde content - Part 2: Colorimetric method
1 Scope
This part of GB/T 19941 specifies a colorimetric method for the determination of free and hydrolyzed formaldehyde content in leathers and furs.
This standard is applicable to the determination of formaldehyde contents in various leathers, furs and their products.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.
GB/T 6682 Water for analytical laboratory use - Specification and test methods (GB/T 6682-2008, ISO 3696: 1987, MOD)
GB/T 19941.1 Leather and fur - Determination of formaldehyde content - Part 1: High performance liquid chromatography method (GB/T 19941.2-2019, ISO 17226-1: 2018, MOD)
QB/T 1267 Fur - Chemical, physical and mechanical and fastness tests - Sampling location (QB/T 1267-2012, ISO 2418: 2002, MOD)
QB/T 1272 Fur - Preparation of chemical test samples (QB/T 1272-2012, ISO 4044: 2008, MOD)
QB/T 1273 Fur - Chemical tests - Determination of volatile matter (QB/T 1273-2012, ISO 4684: 2005, MOD)
QB/T 2706 Leather - Chemical, physical and mechanical and fastness tests - Sampling location (QB/T 2706-2005, ISO 2418: 2002, MOD)
QB/T 2716 Leather - Preparation of chemical test samples (QB/T 2716-2018, ISO 4044: 2008, MOD)
QB/T 2717 Leather - Chemical tests - Determination of volatile matter (QB/T 2717-2018, ISO 4684: 2005, MOD)
3 Principle
The specimen is extracted with an extraction solution under specified conditions, and the obtained extraction solution is mixed with acetylacetone, whereby formaldehyde reacts to give a yellow compound (3,5-diacetyl-1,4-dihydrolutidine). The absorbance of this compound is measured at the specified wavelength, and the formaldehyde content in the specimen is calculated.
Note 1: The determination result of this method is taken to be the quantity of free and hydrolyzed formaldehyde extracted from the leather under standard conditions.
GB/T 19941.2-2019 The following standards are cited:
GB/T 19941.2-2019 Cited by the following standards: