Method I in this standard specifies the gas chromatography - mass spectrometry (GC-MS) for determining the benzenehexachloride (HCH), dichlorodiphenyl trichloroethane (DDT), hexachlorobenzene (HCB), heptachlor, heptachlor eqoxide, chlordane, aldrin, dieldrin, endrin, mirex, pentachloronitrobenzene (PCNB), endosulfan, fenson, allethrin, 2, 4-diehlorophenyl benzensulfonate, ovex, tetramethrin, fenpropathrin, permethrin, cypermethrin, fenvalerate and deltamethrin in animal original foods.
Method II in this standard specifies the gas chromatography - electron capture detector (GC-ECD) for determining the HCH, DDT, PCNB, heptachlor, heptachlor eqoxide, aldrin, dieldrin, fenson, ovex, tetramethrin, permethrin, cypermethrin, α-fenvalerate and deltamethrin in animal original foods.
Method I in this standard is applicable to the verification analysis of α-HCH, HCB, β-HCH, γ-HCH, PCNB, δ-HCH, PCA, heptachlor, PCPs, aldrin, oxy-chlordane, heptachlor eqoxide, trans-chlordane, α-endosulfan, cis-chlordane, p, p’-DDE, dieldrin, endrin, β-endosulfan, p, p’-DDD, o, p’-DDT, endrin aldehyde, endosulfan sulfate, p,p’-DDT, endrin ketone, mirex, fenson, allethrin, 2, 4-diehlorophenyl benzensulfonate, ovex, tetramethrin, fenpropathrin, permethrin, cypermethrin, fenvalerate and deltamethrin in meat, eggs, milk foods and grease (containing vegetable oil).
Method II in this standard is applicable to the pesticide residue analysis for 20 kinds of common organochlorine pesticide and pyrethroid such as α-HCH, β-HCH, γ-HCH, δ-HCH, PCNB, heptachlor, heptachlor eqoxide, aldrin, dieldrin, fenson, ovex, p, p’-DDE, p, p’-DDD, o, p’-DDT, p, p’-DDT, tetramethrin, permethrin, cypermethrin, α-fenvalerate and deltamethrin in meat, eggs and milk animal original foods.
Pesticide detection limit (μg/kg) in Method I of this standard is as follows: α-HCH 0.20, HCB 0.20, β-HCH 0.20, γ-HCH 0.20, PCNB 0.50, δ-HCH 0.20, PCA 0.50, heptachlor 0.50, PCPs 0.50, aldrin 0.50, oxy-chlordane 0.20, heptachlor eqoxide 0.50, trans-chlordane 0.50, α-endosulfan 0.50, cis-chlordane 0.20, p, p’-DDE 0.20, dieldrin 0.20, endrin 0.50, β-endosulfan 0.50, p, p’-DDD 0.20, p, p’-DDT 0.20, endrin aldehyde 0.50, endosulfan sulfate 0.50, p,p’-DDT 0.20, endrin ketone 0.50, mirex 0.20, fenson 0.50, allethrin 0.50, 2, 4-diehlorophenyl benzensulfonate 0.50, ovex 0.50, tetramethrin 1.00, fenpropathrin 1.00, permethrin 1.00, cypermethrin 2.00, fenvalerate 2.00 and deltamethrin 2.00.
Pesticide detection limit (μg/kg) in Method II of this standard is as follows: α-HCH 0.25, β-HCH 0.50, γ-HCH 0.25, δ-HCH 0.25, PCNB 0.25, heptachlor 0.50, heptachlor eqoxide 0.50, aldrin 0.25, dieldrin 0.50, fenson 1.5, ovex 1.25, p, p’-DDT 0.50, o, p’-DDT 0.50, p, p’-DDE 0.60, p, p’-DDD 0.75, tetramethrin 12.50, permethrin 7.50, cypermethrin 2.00, α-fenvalerate 2.50 and deltamethrin 2.50.
前言Ⅲ
1 范围1
第一法 气相色谱质谱法
2 原理1
3 试剂1
4 仪器3
5 分析步骤3
6 结果计算5
7 精密度5
第二法 气相色谱电子捕获检测器法(GCECD)
8 原理5
9 试剂5
10 仪器6
11 分析步骤6
12 结果计算8
13 精密度8
附录A (资料性附录) 第一法(GCMS)中各目标化合物时间窗口及定量离子9
附录B (资料性附录) 色谱图11
附录C (资料性附录) 方法的不确定度16
